摘要
A 2D copper coordination polymer of [Cu2(3-PyOH)2(EDTA)]n (EDTA4-=ethylenediaminetetraacetate quadrivalent anion C10H12N2O8, 3-PyOH=3-hydroxypyridine) was synthesized and characterized by the element analysis, IR and single crystal X-ray diffraction. The title complex crystallizes in monoclinic system with space group P21/c, a=1.3275(3) nm, b=0.93039(19) nm, c=0.94844(19)nm, β=108.21(3)°, and V=1.1128(4) nm3, Z=2, R=0.0252, wR=0.0661. Each copper(Ⅱ) atom is five-coordinated by three O atoms and one N atom from two different EDTA4-groups and one N atom from 3-PyOH ligand, forming a distorted square-pyramidal coordination geometry. Two adjacent copper(Ⅱ) atoms are bridged by the bis-tetradentate EDTA4- groups, constructing a two-dimensional layer structure along bc plane. The adjacent Cu…Cu distances are 0.5025(3) and 0.6113(3) nm.
A 2D copper coordination polymer of [Cu2（3-PyOH）2（EDTA）]n （EDTA4^-=ethylenediaminetetraacetate quadrivalent anion C10H12N2O8, 3-PyOH=3-hydroxypyridine） was synthesized and characterized by the element analysis, IR and single crystal X-ray diffraction. The title complex crystallizes in monoclinic system with space group P2 1/c, a=1.327 5（3） nm, b=0.930 39（19） nm, c=0.948 44（19） nm, β=108.21（3）°, and V=1.112 8（4） nm^3, Z=2, R =0.025 2, wR =0.066 1. Each copper（Ⅱ） atom is five-coordinated by three O atoms and one N atom from two different EDTA^4- groups and one N atom from 3-PyOH ligand, forming a distorted square-pyramidal coordination geometry. Two adjacent copper（Ⅱ） atoms are bridged by the bis-tetradentate EDTA^4- groups, constructing a twodimensional layer structure along bc plane. The adjacent Cu…Cu distances are 0.502 5（3） and 0.611 3（3） nm. CCDC： 618806.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第3期555-557,共3页
Chinese Journal of Inorganic Chemistry
基金
黑龙江省自然科学基金(No.B200501)
黑龙江省高校骨干教师资助项目(No.1054G036)
关键词
铜配位聚合物
合成
晶体结构
copper coordination polymer
synthesis
crystal structure
