摘要
A coordination polymer, {Cu4(nip)4(4,4′-bipy)4(DMF)4·CH3OH}n, have been synthesized by the layer method using 5-nitroisophthalic acid (H2nip), Cu(CH3COOH)2 and 4,4′-bipyridine(4,4′-bipy) with three solutions in a marrow tube and structurally characterized by X-ray single-crystal structure analysis. The results indicated that the nip ligand has a μ2 mono-atomic bridging-monodentate coordination mode and the structure is a two-dimensional network. CCDC: 623420.
A coordination polymer, {[Cu4（nip）4（4,4＇-bipy）4（DMF）4]·CH3OH}n,have been synthesized by the layer method using 5-nitroisophthalic acid （H2nip）, Cu（CH3COOH）2 and 4,4＇-bipyridine（4,4＇-bipy） with three solutions in a marrow tube and structurally characterized by X-ray single-crystal structure analysis. The results indicated that the nip ligand has a μ2 mono-atomic bridging-monodentate coordination mode and the structure is a twodimensional network. CCDC： 623420.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第12期2239-2241,共3页
Chinese Journal of Inorganic Chemistry
