摘要
以多电子原子精细结构哈密顿的球张量形式和氦原子非相对论性能级结构理论为基础,借助不可约张量理论,建立了计算氦原子自旋-其它轨道相互作用精细结构参数的一种解析理论形式.完成了所有的角向积分和自旋求和计算,自旋-其它轨道相互作用精细结构参数最终用若干个径向积分来表示.以氦原子(1s2p)3P态为例,借用类氢形式的径向函数对这些径向积分进行了近似计算.计算结果表明:在氦原子的精细结构中,自旋-其它轨道相互作用与纯自旋-轨道相互作用的作用效果相反;在总自旋-轨道相互作用精细结构参数中,自旋-其它轨道相互作用起决定性作用,它决定着精细结构分裂的顺序.
Based on the tensor expression of the fine structure Hamiltonian and the non-relativistic energy structure theory for helium, and by virtue of irreducible tensor theory, an analytical method for calculating the fine structure parameter for spin-other-orbit interaction in helium-like atoms is established. All the angular integrations and spin summations involved in the problem have been carried out explicitly, the parameter is expressed finally as a sum of some radial integrations. Approximate evaluation for these radial integrations in the (1s2p)^3P state of helium is outlined, in which the hydrogen-like radial functions are employed. It is found that in the fine structure of helium, the spin-other-orbit interaction and the pure spin-orblt interaction act in the opposite directions, and it is the former that plays the most important role, which determines the splitting order of the fine structure.
出处
《原子与分子物理学报》
CAS
CSCD
北大核心
2006年第6期1138-1144,共7页
Journal of Atomic and Molecular Physics
基金
国家人事部留学人员科技活动项目择优资助项目(2005LXAH06)
安徽省教育厅高校省学术带头人后备人选科学研究基金(2002HBL05)
安徽省教育厅自然科学基金重点项目(2003KJ035ZD)
安徽省原子与分子物理重点学科建设基金(2002ZDXK)