摘要
本文介绍了合成分子印迹聚合物的功能单体中间体——甲基丙烯酰氯的合成方法,并对其红外光谱进行表征,同时与丙烯酰氯、苯甲酰氯红外光谱比较发现1756cm^(-1)、1736cm^(-1)峰是v c=0与878.27cm^(-1)倍频峰之间发生费米共振而产生双峰。
The synthesis method of methacryloyl chloride, which is the intermediate of functional monomer of molecular imprinted polymer, was described in this paper, and the methacryloyl chloride was characterized by infrared spectrum. The infra-red spectrogram of methacryloyl chloride was compared with acryloyl chloride and benzoyl chloride and found that 1765cm^-1 and 1736cm^-1 is the double peak produced form Fermi sympathetic vibration between the peak of v c=0 and 878.27cm^-1 double frequency peak.
出处
《齐齐哈尔大学学报(自然科学版)》
2006年第5期21-23,30,共4页
Journal of Qiqihar University(Natural Science Edition)
基金
黑龙江省教育厅科学技术研究项目(项目编号:11511435)
关键词
甲基丙烯酰氯
红外光谱
费米共振
methacryloyl chloride
infra-red spectrum
Fermi sympathetic vibration