摘要
报道了一种新颖的配位聚合物[Cu4(Ophen)4(tp)]的水热合成和晶体结构.该化合物属于单斜晶系,P21/n空间群,a=1.02973(7)nm,b=1.51015(11)nm,c=1.51869(11)nm,β=104.6070(10)°,V=2.2853(3)nm3,Z=4,T=293(2)K,Dc=1.743 mg/m3,μ=1.908 mm-1,R1=0.0340,wR2=0.0869.标题化合物为Cu(Ⅰ)双核配位聚合物.邻菲咯啉在水热反应中发生羟基化,形成新型的羟基化邻菲咯啉.该化合物展示了蓝色荧光.
A new metal-organic complex [Cu4（Ophen）4（tp）] was hydrothermally synthesized and its structure was characterized by the single crystal X- ray diffraction. The compound crystallizes in the monoclinic, space groupP2 1/n with a = 1.02973（7） nm, b = 1.51015（11） nm, c = 1.51869（11） nm,β= 104.6070 （10）°, V =2.2853（3） nm^3,Z=4, T =293（2） K,Dc = 1.743 Mg/m^3,μ = 1.908 mm^-1,Rl =0.0340, ωR2 = 0.0869. The compound shows blue fluorescence.
出处
《吉林师范大学学报（自然科学版）》
2006年第3期69-70,共2页
Journal of Jilin Normal University:Natural Science Edition
关键词
羟基化邻菲咯啉
原位合成
晶体结构
hydroxylation of phenanthroline
in - situ synthesis
crystal structure
