摘要
The Maoniuping REE deposit, located about 22 km to the southwest of Mianning, Sichuan Province, is the second largest light REE deposit in China, subsequent to the Bayan Obo Fe-Nb-REE deposit in the Inner Mongolia Autonomous Region. Tectonically, it is located in the transitional zone between the Panxi rift and the Longmenshan-Jinpingshan orogenic zone. It is a carbonatite vein-type deposit hosted in alkaline complex rocks. The bastnaesite-barite, bastnaesite-calcite, and bastnaesite- microcline lodes are the main three types of REE ore lodes. Among these, the first lode is distributed most extensively and its REE mineralization is the strongest. The δ^34Sv.cDT values of the barites in the ore of the deposit vary in a narrow range of +5.0 to +5.1‰ in the bastnaesite-calcite lode and +3.3 to +5.9‰ in the bastnaesite-barite lode, showing the isotopic characteristics of magma-derived sulfur. The δ^13Cv-PDB values and the δ^Ov.SMOW values in the bastnaesite-calcite lode range from -3.9 to -6.9‰ and from +7.3 to +9.7 ‰, respectively, which fall into the range of "primary carbonatltes", showing that carbon and oxygen in the ores of the Maoniuping deposit were derived mainly from a deep source. The δ^13Cv.PDB values of fluid inclusions vary from -3.0 to -5.6‰, with -3.0 to -4.0‰ in the bastnaesitecalcite lode and -3.0 to -5.6‰ in the bastnaesite-barite lode, which show characteristics of mantle- derived carbon. The δDv-SMOW values of fluid inclusions range from -57 to -88‰, with -63 to -86‰ in the bastnaesite-calcite lode and -57 to -88‰ in the bastnaesite-barite lode, which show characteristics of mantle-derived hydrogen. The δ^18OH2OV.SMOW values vary from +7.4 to +8.6‰ in the bastnaesitecalcite lode, and +6.7 to +7.8‰ in the bastnaesite-barite lode, almost overlapping the range of +5.5 to +9.5‰ for magmatic water. The 4He content, R/Ra ratios are (13.95 to 119.58)×10^-6 (cm^3/g)STP and 0.02 to 0.11, respectively, and ^40Ar/^36Ar is 313± 1 to 437 ±
The Maoniuping REE deposit, located about 22 km to the southwest of Mianning, Sichuan Province, is the second largest light REE deposit in China, subsequent to the Bayan Obo Fe-Nb-REE deposit in the Inner Mongolia Autonomous Region. Tectonically, it is located in the transitional zone between the Panxi rift and the Longmenshan-Jinpingshan orogenic zone. It is a carbonatite vein-type deposit hosted in alkaline complex rocks. The bastnaesite-barite, bastnaesite-calcite, and bastnaesite- microcline lodes are the main three types of REE ore lodes. Among these, the first lode is distributed most extensively and its REE mineralization is the strongest. The δ^34Sv.cDT values of the barites in the ore of the deposit vary in a narrow range of +5.0 to +5.1‰ in the bastnaesite-calcite lode and +3.3 to +5.9‰ in the bastnaesite-barite lode, showing the isotopic characteristics of magma-derived sulfur. The δ^13Cv-PDB values and the δ^Ov.SMOW values in the bastnaesite-calcite lode range from -3.9 to -6.9‰ and from +7.3 to +9.7 ‰, respectively, which fall into the range of "primary carbonatltes", showing that carbon and oxygen in the ores of the Maoniuping deposit were derived mainly from a deep source. The δ^13Cv.PDB values of fluid inclusions vary from -3.0 to -5.6‰, with -3.0 to -4.0‰ in the bastnaesitecalcite lode and -3.0 to -5.6‰ in the bastnaesite-barite lode, which show characteristics of mantle- derived carbon. The δDv-SMOW values of fluid inclusions range from -57 to -88‰, with -63 to -86‰ in the bastnaesite-calcite lode and -57 to -88‰ in the bastnaesite-barite lode, which show characteristics of mantle-derived hydrogen. The δ^18OH2OV.SMOW values vary from +7.4 to +8.6‰ in the bastnaesitecalcite lode, and +6.7 to +7.8‰ in the bastnaesite-barite lode, almost overlapping the range of +5.5 to +9.5‰ for magmatic water. The 4He content, R/Ra ratios are (13.95 to 119.58)×10^-6 (cm^3/g)STP and 0.02 to 0.11, respectively, and ^40Ar/^36Ar is 313± 1 to 437 ±