摘要
以六氮杂三环十四烷并双呋咱(HTTD)[Ⅰ]为原料进行硝化,合成了五硝基六氮杂三环十四烷并双氧化呋咱(PHTTD)[Ⅱ]、乙酰基五硝基六氮杂三环十四烷并双氧化呋咱二水合物(APHTTD)[Ⅲ]和PHTTD[Ⅱc]及PHTTD[Ⅱ]与含氧分子(H2O、二氧六环等)形成相应的分子配合物[Ⅱa]、[Ⅱb]等,与含氧分子形成配(缔)合物是呋咱和氧化呋咱型稠环硝胺单质化合物的共性。利用元素分析、红外光谱、质谱对其结构进行了鉴定。
4,7,9,11,14-pentanitro-2,4,7,9,11,14-hexaazatricych, [ 8 · 4 · 0 · 0^3.8] tetradeeane-5,6,12,13-difuroxan （ PHTTD ） [ Ⅱ] and 2-achyl-4, 7, 9, 11, 14-pentanitro-2, 4, 7, 9, 11, 14-hexaazatrieyelo [8 · 4 · 0 · 0^3.8 ] tetradecane-5,6, 12, 13- difuroxan · 2H2O（APHTTD） [ Ⅲ ] and PHTTD[ Ⅱ c ] were synthesized from nitration of HTrD[ Ⅰ ] ; PHTD · 2H2O[ Ⅱ a] and PHTTD· dioxane[ Ⅱ hi were synthesized from reaction of PHTTD [ Ⅱ ] and water（ or dioxane）. Nitrated products forming molecular complexes with the molecules containing oxygen was general character of furazan and furoxan-fused cylic compounds of nitramines. Their structures were characterized by elemental analysis,IR and MS spectra.
出处
《含能材料》
EI
CAS
CSCD
2006年第4期262-264,共3页
Chinese Journal of Energetic Materials
关键词
有机化学
呋咱
氧化呋咱
稠环硝胺
配合物
高能量密度材料
organic chemistry
furazan
furoxan
fused cyclic nitramine
coordination compound
high energy density material
