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锌膏增稠剂对锌电极及锌-空气电池性能的影响 被引量:3

Effect of zinc gel binder on zinc-air battery and zinc electrode
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摘要 为了改善锌电极及锌-空气电池的性能,通过对比试验分析了羧甲基纤维素钠(CMC)和聚丙烯酸钠(PAAS)对锌电极电化学性能以及锌-空气电池放电性能的影响。结果表明:采用CMC与PAAS以一定比例混合用作锌膏增稠剂,使锌膏具有良好的电化学性能和电池放电性能。所装配的AA型锌-空气电池采用10Ω恒阻连续放电方式进行放电,终止电压为0.9V,电池的放电时间达到39h以上,在1.235V左右有一个平坦的放电平台,锌粉的利用率为83.1%,电池的放电容量达到4770mAh。 In order to improve the performance of zinc electrode, effect of sodium carboxymethyl cellulose (CMC) and polyacrylate sodium on electrochemical performance of zinc electrode and discharge performance of zinc-air battery were analyzed by contrast experiments. It showed that using the mixture of CMC and polyacrylate sodium as zinc gel binder, zinc electrode and zinc-air battery had better performances than others. AA size zinc-air battery was made with this zinc gel binder. It discharged for 39 h before voltage reached 0.9 V with 10Ω constant load. The discharge curve of the cell had a flat plateau at 1.235 V,utilization of zinc powder was 83.1%. Its discharge capacity reached 4 770 mAh.
出处 《电源技术》 CAS CSCD 北大核心 2006年第8期630-632,671,共4页 Chinese Journal of Power Sources
基金 黑龙江发展高新技术项目基金(20020101)
关键词 锌电极 锌-空气电池 锌膏增稠剂 交流阻抗 zinc-air battery zinc electrode zinc gel binder AC impedance
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参考文献4

  • 1JONATHAN G. New development of the electric fuel zinc/air systerm[J]. J Power Sources, 1999,80:171- 179. 被引量:1
  • 2YOSHINOBU M. Makers re-examine zinc-air batteries in light of high-tech advances[J]. JEE, 1991,83(7):82. 被引量:1
  • 3吉田和正.改性的锌膏粘接剂[P].日本:公开昭58-73956,1983-05-04. 被引量:1
  • 4富士电气化学株式会社[P].日本:特许公报2776396,1998-05-01. 被引量:1

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