摘要
A new flow injection chemiluminescence method for the determination of paeonol was established.The method was based on chemiluminescence reaction of paeonol with Ce（Ⅳ） in sulfuric acid condition sensitized by rhodamine 6G.The method is simple,convenient and sensitive.The linear relationship between the intensity of chemiluminescence and the concentration of paeonol is over the range of 5.0×10-7 ～1.0×10-4mol/L.The detection limit is 9.7×10-8 mol/L,the relative standard deviation is 1.8 % for 7 measurements of 1.0×10-5mol/L standard solution.This method has been successfully applied to the determination of paeonol in ointment with recovery between 98.8% and 104%,and the results were in good agreement with those obtained by UV method.
A new flow injection chemiluminescence method for the determination of paeonol was established. The method was based on chemiluminescence reaction of paeonol with Ce （ IV ） in sulfuric acid condition sensitized by rhodamine 6G. The method is simple, convenient and sensitive. The linear relationship between the intensity of chemiluminescence and the concentration of paeonol is over the range of 5. 0 × 10^-7 - 1. 0 × 10-4mol/L. The detection limit is 9. 7 × 10^-8 tool/L, the relative standard deviation is 1. 8 % for 7 measurements of 1. 0 × 10^-5 mol/L standard solution. This method has been successfully applied to the determination of paeonol in ointment with recovery, between 98. 8% and 104%, and the results were in good agreement with those obtained by UV method.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第7期886-888,共3页
Chemical Research and Application
基金
广西青年科学基金资助项目(桂科青0135003)
广西高校百名中青年学科带头人资助计划资助项目(桂教人[2002]467)
