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含有1-苯基-3-苯甲酰基硫脲端基的开链冠醚的合成(Ⅱ)

SYNTHESIS OF NONCYCLIC CROWN ETHERS WITH 1 PHENYL 3 BENZOYL THIOCARBAMIDE AS TERMINAL GROUPS(Ⅱ)
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摘要 由苯甲酰基异硫氰酸酯、开链冠醚桥连二芳胺合成了3种以1-苯基-3-苯甲酰基硫脲为端基的开链冠醚,并用IR,1HNMR,MS等谱验证了其结构。 Three noncyclic crown ethers with 1 phenyl 3 benzoyl thiocarbamide as terminal groups were synthesized by treating diaromatic amides bridged in noncyclic crown ether with benzoyl isothiocyanate by refluxing acetone. The structures of these compounds were confirmed by infrared spectra, 1 HNMR spectra and mass spectra. And the coordination capacity of these compounds with some metal ion were preliminarily examined.
出处 《广西师范大学学报(自然科学版)》 CAS 1996年第2期58-61,共4页 Journal of Guangxi Normal University:Natural Science Edition
关键词 冠醚 开链冠醚 苯基 苯甲酰基 硫脲 端基 合成 noncyclic ether 1 phenyl 3 benzoyl thiocarbamide terminal group synthesis
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