摘要
双酚Ａ和邻苯二甲酰氯芳香酯环状低聚物经硝基笨重结晶得到环状四聚体，利用ＧＰＣ、ＭＳ（ＦＡＢ）、１ＨＮＭＲ、ＩＲ、ＤＳＣ和元素分析对其结构进行了表征。其晶体结构由广角Ｘ射线衍射法确定为正交晶系，晶胞参数为α＝０．９６７６ｎｍ，ｂ＝０．８６９９ｎｍ，ｃ＝２．０８５９ｎｍ。每个晶胞中含有２个环状四聚体分子，晶体密度为１．３６ｇ·ｃｍ－３，对环状四聚体晶体衍射峰进行了详细的指标化。
The polycrystalline powder of the cyclic tetramer based on bisphenol A and o-phthaloyldichloride has been prepared by recrystallization from nitrobenzene and its crystalstructure has been determined by Wide-Angle X-ray Diffraction( WAXD ).The unit cell is orthorhombic and its dimensions α=0.967 b=0. 869 9 nm,c=2. 085 9 nm.Space group belongs to Pmmm,With two tetramers per unit cell, the crystal density is 1.36 g·cm-3.Indices of crystal diffraction peaks are also detailed in the present work.
出处
《高等学校化学学报》
CSCD
北大核心
1996年第8期1310-1313,共4页
Chemical Journal of Chinese Universities
基金
福特中国研究与发展基金
