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非晶碳膜中sp^2和sp^3相的检测方法 被引量:16

The Characterization Methods Used to Determine sp^2 and sp^3 Bonding Carbon of Amorphous Carbon Film
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摘要 非晶碳薄膜由sp2和sp3杂化的碳原子组成。sp2和sp3碳原子的比例是决定非晶碳膜的结构和性能的重要参数。如何定量或定性地分析碳薄膜中sp2和sp3碳的含量一直是十分重要的问题。目前用来测定sp2和sp3碳及其比例的实验方法有13C核磁共振谱(NMR)、电子能量损失谱(EELS)、X射线光电子能谱(XPS)、椭圆偏振谱、拉曼光谱(Raman)、红外光谱(IR)等。综述了这些测定方法及其特点。 Amorphous carbon film is composed of sp^2 bonding and spa bonding carbon atoms. The ratio of sp^2/sp^3 bonding carbon is an important parameter to determine the structure and properties of amorphous film. So it is important to analyze the sp^2 and sp^3 content in amorphous carbon film qualitatively or quantitatively. Various characterization methods have been used to determine those parameters such as ^13C nuclear magnetic resonance spectrometry (NMR), electron energy loss spectroscopy (EELS), X-ray photoelectron spectroscopy(XPS), elliptical polarization spectroscopy(EP), Raman spectroscopy (Raman),infrared spectroscopy (IR). This review will describe these methods.
出处 《材料导报》 EI CAS CSCD 北大核心 2006年第6期98-101,共4页 Materials Reports
基金 教育部科学技术研究重点项目(205091)
关键词 非晶碳膜 sp^2碳 sp^3碳 检测方法 amorphous carbon film, sp^2 bonding carbon, spa bonding carbon,characterization methods
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