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^(13)C-NMR波谱法研究乙丙共聚物的微观序列结构 被引量:5

Study on sequential structure of ethylene-propylene copolymer by high resolution ^(13)C-NMR
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摘要 利用索氏抽提分离、升温淋洗分级对乙丙共聚物进行分级,对分级后的级分做核磁共振碳谱测试。研究了乙丙共聚物的链段存在形式,讨论了不同级分试样结构上的差别,建立了适合工业生产和科研开发过程中评价产品序列结构的方法。 The ethylene-propylene copolymer fractionation; the treated specimens were was pretreated by Soxhlet extraction and temperature-rising elution analyzed with carbon spectrum of nuclear magnetic resonance. The discrepancy in micro-sequential structure was elucidated for the specimens fractionated at different temperatures in TREF process. A method for evaluating the micro-sequential structure was established, which could be used in both the commercial production and scientific development process.
出处 《合成树脂及塑料》 EI CAS 北大核心 2006年第3期60-63,共4页 China Synthetic Resin and Plastics
关键词 乙丙共聚物 核磁共振碳谱 索氏抽提 升温淋洗分级 微观序列结构 ethylene-propylene copolymer nuclear resonance magnetic spectrometry Soxhlet extraction temperature-rising elution fractionation micro-sequential structure
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参考文献4

  • 1Cai Hongjun, Luo Xiaojie, Ma Dezu, et al. Structure and properties of impact copolymer polypropylene, Ⅰ. Chain structure [J]. Journal of Applied Polymer Science, 1999. 71(1): 93-101 被引量:1
  • 2Cai Hongjun, Luo Xiaojie, Chen Xiangxu, et al. Structure and properties of impact copolymer polypropylene, Ⅱ. Phase structure and crystalline morphology [J]. Journal of Applied Polymer Science,1999, 71(1): 103-113 被引量:1
  • 3Feng Y, Hay J N. The characterization of random propylene-ethylene copolymer []]. Polymer, 1998, 39 (25): 6 589-6 596 被引量:1
  • 4吴春红,周学秋.^(13)C-NMR和近红外光谱研究PP序列结构[J].合成树脂及塑料,2001,18(2):10-12. 被引量:5

二级参考文献2

  • 1朱善农 杨小震.-[J].高分子通讯,1981,(4):263-263. 被引量:1
  • 2朱善农 杨小震.-[J].高分子通讯,1984,(6):97-201. 被引量:1

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