摘要
倒浮萍聚合物LB膜的有序-无序相变研究李宏斌,张希,张瑞丰,赵冰,徐尉青,沈家骢,高忠民(吉林大学分子光谱与分子结构开放实验室、化学系,分析测试中心,长春,130023)关键词聚合物LB膜,有序-无序相变,变温红外光谱,变温小角X光衍射LB膜的有序-...
The order-disorder transition in“Reversed Duckweed”type polymeric LB filmwas investigated by temperature-dependent infrared transmition and X-rav diffraction. Threesteps of melting process were obtserved :the first and second steps were reversible transitionscorresponding to the disorder of the alkyl chains in each layer,and the layer structure wasmaintained;the third was an irreversible transition corresponding to the melting of the two-dimension system,and the layer structure was damaged during this phase transition process.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第1期160-161,共2页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
国家教育委员会优秀跨世纪人才基金
关键词
聚合物
LB膜
有序-无序相变
红外光谱
Polymeric LB film, Order-disorder transition,Temperature-dependent IR,Tem-perature-dependent low-angle X-ray diffraction