摘要
以对乙酰氨基苯甲醛、间乙酰氨基苯乙酮为原料经两步反应合成具有光敏性能的1-(3-氨基苯基)-3-(4-氨基苯基)-2-丙烯-1-酮.采用溶液缩聚及化学亚胺化法制备了相应的光敏聚酰亚胺.光敏性二胺经液相色谱分析其纯度分别为99.92%,紫外可见最大吸收波长为349nm.光敏聚酰亚胺的耐热温度超过400℃,紫外可见最大吸收波长为365nm.所得方法操作简便,收率较高,原料易得.并用元素分析、核磁共振、红外光谱等手段对产物的结构进行了表征.
The photosensitive 1 - （ 3 - aminophenyl） - 3 - （4 - aminophenyl） - 2 - propen - 1 - one was prepared using the materials 3 - acetylacetanilide and 4 - acetamidobenzaldehyde through two steps of reaction. The corresponding photosensitive polyimide was synthesized by solution polymerization and chemically conversion. The purity was 99. 92% by the analysis of HPLC and the maximal absorption wavelength of uv - vis spectrum was 349nm. The heat -resist temperature of photosensitive polyimide was over 400℃ with the maximal absorption wavelength of uv - vis spectrum 365nm. The method had the advantages of cheapness, high yield and easy operation. Elemental analysis, HNMR and IR were used to characterize the target compounds.
出处
《材料科学与工艺》
EI
CAS
CSCD
北大核心
2006年第1期66-67,112,共3页
Materials Science and Technology
基金
国家高技术研究发展计划资助项目(2002AA325110)
