摘要
通过一步法合成线性聚二氯磷腈(PDCP),并用对羟基苯甲酸甲酯与线性聚二氯磷腈(PDCP)反应合成聚双(对羟基苯甲酸甲酯)磷腈,运用~1HNMR、^(13)C NMR、^(31)P NMR及FT-IR对其结构进行了表征。DSC和TGA实验表明该聚合物的T_g有了明显的提高且具有较好的热稳定性。
Linear polydiehlorophosphazene was synthesized via one-step synthesis method. Poly [bis （methyl p-hydroxybenzoate） phosphazenel was obtained by the reaction of methyl p-hydroxybenzoate with linear polyhalophosphazene, and was characterized by ^1H NMR, ^13C NMR, ^31p NMR and FT-IR. Thermal property was determined by DSC and TGA. It is found that Tg of the polymer increased obviously and the polymer possessed good thermal stability.
出处
《化学通报》
CAS
CSCD
北大核心
2006年第2期140-143,共4页
Chemistry
