摘要
用氨基磺酸为催化剂,实现了甲酸与环己醇反应合成甲酸环己酯。考察了催化剂用量,原料配比,酯化时间,带水剂种类等因素对合成反应的影响,确定了最佳反应条件,最佳条件为n(醇)∶n(酸)=1∶2,催化剂用量为醇质量的5.3%,反应时间为1.0h,产率可达80.7%,催化剂具有可循环使用等优点。
Aminosulfonic acid is used as the catalyst for preparing cyclohexyl formate. The factors that affect on reaction were studied. The optimal condition as follows： molar ratio of cyclohexanol to formic acid was 1： 2, reaction time of reflux was 1. 0 h, mass of catalyst was 5.3% of cyclohexanol. The yield of esterification may reach 80.7% in the condition.
出处
《湖北师范学院学报（自然科学版）》
2005年第4期78-80,共3页
Journal of Hubei Normal University(Natural Science)
关键词
氨基磺酸
催化酯化
甲酸环己酯
aminosulfonic acid
esterification
cyclohexylformate
