摘要
通过溶剂热法合成了一种新的2-吡啶硫醇-铜六核配合物Cu6(C5H4NS)6,用红外光谱、元素分析、热分析对其进行表征。对影响反应的主要因素,如反应物摩尔比、反应溶剂、pH值、反应温度等进行系统研究,确定了最佳反应条件为:CuCl和2,2′-二吡啶基二硫化合物(btdp)的摩尔比为2∶1,溶剂为水,pH=7,150℃反应5 d。
A new coordination compound of Cu6 （CsH4NS）6 was prepared by solvothermal sythesis and characterized by IR, TG and thermal analysis. The reaction conditions such as the mole ratio, solvents, pH value and the reaction temperature were systematicly investigated and the optimum conditions of this reaction were determined： the mole ratio of CuCl to 2, 2＇-bisthiodipyridine is 2：1, with H2O under 150 ℃ for 5 days.
出处
《北京化工大学学报（自然科学版）》
CAS
CSCD
北大核心
2005年第5期75-77,共3页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
关键词
多核配合物
吡啶硫醇金属配合物
溶剂热法
热稳定性
multinuclear coordination compound
thiopyridine metal compound
solvothermal synthesis
thermal stability
