摘要
A manganese coordination polymer [（phen）MnCl2]n （phen=1,10-phenanthroline, C12H8N2） with formula C12H8Cl2MnN2 and Mr=306.04 has been synthesized and structurally characterized by single-crystal X-ray diffraction. The crystal is of monoclinic, space group C2/c with a=17.2451 （10）, b=10.4431 （8）, c=7.0349（5）A°, β= 111.983（1）°, V=1174.82（14） A°^3, Z=4, Dc=1.730 g/cm^3, μ=1.552 mm^-1, F（000）=612, T=293（2） K, R=0.0343 and wR=0.0877 for 826 observed reflections with I〉2σ（I）. The title compound possesses a one-dimensional chain structure composed of polymeric （phen）MnCl2 units in which the manganese （Ⅱ） ion is chelated by one phen and bridged by double chloro-ligands with the Mn-N distance of 2.257（3）A° and Mn-Cl of 2.4775（8） and 2.6568（7）A°. The Mn…Mn separation is 3.853A°.
A manganese coordination polymer [（phen）MnCl2]n （phen=1,10-phenanthroline, C12H8N2） with formula C12H8Cl2MnN2 and Mr=306.04 has been synthesized and structurally characterized by single-crystal X-ray diffraction. The crystal is of monoclinic, space group C2/c with a=17.2451 （10）, b=10.4431 （8）, c=7.0349（5）A°, β= 111.983（1）°, V=1174.82（14） A°^3, Z=4, Dc=1.730 g/cm^3, μ=1.552 mm^-1, F（000）=612, T=293（2） K, R=0.0343 and wR=0.0877 for 826 observed reflections with I〉2σ（I）. The title compound possesses a one-dimensional chain structure composed of polymeric （phen）MnCl2 units in which the manganese （Ⅱ） ion is chelated by one phen and bridged by double chloro-ligands with the Mn-N distance of 2.257（3）A° and Mn-Cl of 2.4775（8） and 2.6568（7）A°. The Mn…Mn separation is 3.853A°.
基金
Supported by NNSFC (No. 30170229 and 20271061)
