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含轴手性磺酸配体的镉配合物(英文)

Cd(Ⅱ) Complex with Disulfonate Atropisomeric Ligand
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摘要 The crystal structure of Cd(BDA)(phen)2(H2O)(H2O)2 (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-bi- naphthylene-4,4′-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination envi- ronment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen lig- ands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interac- tions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921. The crystal structure of [Cd(BDA)(phen)2(H2O)](H2O)2 (1) (BDA=6,6'-dibromo-2,2'-dimethoxy-1,1'-binaphthylene-4,4'-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination environment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen ligands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interactions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921.
作者 唐云志 周挺
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2005年第9期1435-1436,共2页 Chinese Journal of Inorganic Chemistry
基金 973项目(No.G2000077500)资助项目
关键词 晶体结构 6 6’-二溴-2 2'-二甲氧基-1.1’-二萘-4 4'-二磺酸 crystal structure 6,6'-dihromo-2,2'-dimethoxy- 1,1 '-binaphthylene-4,4 '-disulfonic acid cadmium
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