期刊文献+

电化学一锅法合成荧光碳纳米点用于检测过氧化氢(英文) 被引量:3

A Facile Electrochemical Method to Synthesize Fluorescent Carbon Nanodots for Hydrogen Peroxide Sensing
下载PDF
导出
摘要 利用一种简易的电化学一锅法合成了荧光碳纳米点.此种方法没有复杂的后续纯化过程可以一次性获得尺寸均一的纳米碳点(4±1 nm).过氧化氢可以直接将制得的碳纳米点荧光猝灭,当过氧化氢浓度范围在25~300μmol/L时,碳纳米点的荧光猝灭强度与过氧化氢浓度呈较好的线性关系,检测限为3μmol/L.本研究为过氧化氢的检测提供了一种新的简易的方法,在生化传感研究中有着巨大的应用前景. In this work,fluorescent carbon nanodots (C-dots) with sizes of (4 ± 1 ) nm were synthesized through a one-pot electrochemical method without further complicated purification,and the fluorescence of the C-dots can be quenched by hydrogen peroxide directly.The fluorescence intensity (FL)of C-dots was decreased linearly with the hydrogen peroxide concentration in the range of 25 μmol/L to 300 μmol/L,and the detection limit was 3 μmol/L.This may offer a simple and sensitive method in sensing hydrogen peroxide.
出处 《湖南师范大学自然科学学报》 CAS 北大核心 2012年第1期43-47,共5页 Journal of Natural Science of Hunan Normal University
基金 国家自然科学基金资助项目(20975037)
关键词 碳纳米点 电化学一锅法 荧光猝灭 过氧化氢 carbon nanodots one-pot electrochemical method fluorescence quench hydrogen peroxide
  • 相关文献

参考文献14

  • 1XU X Y,Ray R,GUY L. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J].Journal of the American Chemical Society,2004,(40):12736-12737.doi:10.1021/ja040082h. 被引量:1
  • 2YANG S T,WANG X,WANG H F. Carbon dots as nontoxic and high-performance fluorescence imaging agents[J].Journal of Physical Chemistry C,2009,(42):18110-18114.doi:10.1021/jp9085969. 被引量:1
  • 3RAY S C,SAHA A,JANA N R. Fluorescent carbon nanoparticles:synthesis,characterization,and bioimaging application[J].Journal of Physical Chemistry C,2009,(43):18546-18551.doi:10.1021/jp905912n. 被引量:1
  • 4BAKER S N,BAKER G A. Luminescent carbon nanodots:emergent nanolights[J].Angewandte Chemie International Edition,2010,(38):6726-6744.doi:10.1002/anie.200906623. 被引量:1
  • 5SUN Y P,ZHOU B,LIN Y. Quantum-sized carbon dots for bright and colorful photoluminescence[J].Journal of the American Chemical Society,2006,(24):7756-7757.doi:10.1021/ja062677d. 被引量:1
  • 6CAO L,WANG X,LU F S. Carbon dots for multiphoton bioimaging[J].Journal of the American Chemical Society,2007,(27):11318-11319. 被引量:1
  • 7YANG S T,CAO L,LUO P G. Carbon dots for optical imaging in vivo[J].Journal of the American Chemical Society,2009,(32):11308-11309.doi:10.1021/ja904843x. 被引量:1
  • 8LI H T,HE X D,KANG Z H. Water-soluble fluorescent carbon quantum dots and photocatalyst design[J].Angewandte Chemie International Edition,2010,(26):4430-4434.doi:10.1002/anie.200906154. 被引量:1
  • 9SHI W B,WANG Q L,LONG Y J. Carbon nanodots as peroxidase mimetics and their applications to glucose detection[J].Chemical Communications,2011.6695-6697. 被引量:1
  • 10GONCALVES H M R,DUARTE A J,ESTEVES DA SILVA J C G. Optical fiber sensor for Hg(Ⅱ) based on carbon dots[J].Biosensors and Bioelectronics,2010,(04):1302-1306.doi:10.1016/j.bios.2010.07.018. 被引量:1

同被引文献83

  • 1EDA G, LIN Y Y, MATTEVI C, et al. Adv Mater[J],2010,22:505-509. 被引量:1
  • 2SUN Y P, ZHOU B, LIN Y, et al. J Am Chem Soc[J],2006,128:7756-7757. 被引量:1
  • 3XU X Y, RAY R, GU Y L, et al. J Am Chem Soc[J],2004,126:12736-12737. 被引量:1
  • 4BOTTINI M, BALASUBRAMANIAN C, DAWSON M J, et al. J Phys Chem B[J],2005,110:831-836. 被引量:1
  • 5XU J, SAHU S, CAO L, et al. Chem Phys Chem[J],2011,12:3604-3608. 被引量:1
  • 6YANG Z C, WANG M, YONG A M, et al. Chem Commun[J],2011,47:11615-11617. 被引量:1
  • 7CAO L, WANG X, MEZIANI M J, et al. J Am Chem Soc[J],2007,129:11318-11319. 被引量:1
  • 8LI H, HE X, LIU Y, et al. Mater Res Bull[J],2011,46:147-151. 被引量:1
  • 9WANG F, PANG S, WANG L, et al. Chem Mater[J],2010,22:4528-4530. 被引量:1
  • 10LI X, WANG H, SHIMIZU Y, et al. Chem Commun[J],2011,47:932-934. 被引量:1

引证文献3

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部