摘要
Six substituented phenylhydrazines and their complexes with crown ethers (DB-18-crown-6, DB-24-crown-8) were synthesized. Their photolytic process have been studied in the existence of nitrosodurene (ND) by ESR. All of the experimental results indicate that the C-N bond energy decreased when the different substituted phenylhydrazine was complexed by crown ether.
Six substituented phenylhydrazines and their complexes with crown ethers (DB-18-crown-6, DB-24-crown-8) were synthesized. Their photolytic process have been studied in the existence of nitrosodurene (ND) by ESR. All of the experimental results indicate that the C-N bond energy decreased when the different substituted phenylhydrazine was complexed by crown ether.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1995年第4期342-345,共4页
Acta Physico-Chimica Sinica
基金
国家自然科学基金
关键词
苯肼
冠醚
配合物
光解
电子自旋共振
Substituented phenylhydrazine, Crownn ether complex, Photolysis, Spin trapping, ESR
