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用玻璃pH电极作参比电极测定氰含量的研究

Determination of Cyanide with pHGlass Electrode as A Reference Electrode
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摘要 研究了用玻璃pH电极作参比电极测定废水中氰含量的新方法。方法的pCN线性域为1.0~5.5,酸度范围为pH=4~13,回收率为100%~107%,响应时间不大于30s。方法快速简单,样品不需分离,精密度和准确度满足分析要求。 A new potentiometric method for the determination of total cyanide is described, inwhich cyanide electrode served as a senstive electrode and pH glass electrode as a reference elective in basic and acid media. The cyanide electrode exhibited Nernstian response for totalcyanide concentrtion ranging from 10-5.5 to 10-1 mol·L-1 at pH 4~13, the response time wasless than 30s. This method has been applied to determinate the content of cyanide in acid wastewater. It was simple and fast with recovery of 100%~107%.
出处 《西北林学院学报》 CSCD 1995年第4期76-79,共4页 Journal of Northwest Forestry University
关键词 离子选择性电极 氰化物 废水分析 ion selective electrode cyanide waste water analysis
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参考文献2

  • 1黄德培等编著..离子选择电极的原理及应用[M].北京:新时代出版社,1982:423.
  • 2曾北危编著..环境分析化学[M].长沙:湖南科学技术出版社,1979:796.

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