摘要
以粉末白钨酸(WPTA)为催化剂,稀过氧化氢为氧化剂,对α-蒎烯催化异构、氧化、酯化,合成高萜基甲基内酯(HMK).α-蒎烯转化率达100%,HMK得率达84%,HMK经MS、IR、NMR、EA表征.
:Isomerigation, oxidation and esterification of a-pinene catalyzed by white power tungstic acid (WPTA) with diluted hydrogen peroxide. It was an effective synthesis method of homoterpenyl methyl ketone (HMK). The conversion of a-pinene reached 100%. The yield of HMK reached 84% ,HMK was confirmed by MS,IR,1H-NMR,EA.
出处
《江西师范大学学报（自然科学版）》
CAS
1995年第4期342-346,共5页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
国家自然科学基金资助项目
关键词
粉末白钨酸
过氧化氢
催化反应
HMK
合成
蒎烯
white power tungstic acid,α-pinene,homoterpenyl methyl ketone,catalystic oxidation
