摘要
采用放射化学法测定了ＡｇＩ在浓盐溶液中的溶解度。用间歇平衡实验研究了浓盐溶液中碘（Ｉ￣－）在水泥、氢氧化铁和天然岩盐中的吸附行为。研究结果表明，在以上三种吸附体系中，Ｉ￣－浓度为１０￣（－７）－１０￣（－４）ｍｏｌ／ｌ时，Ｉ￣－的吸附比（Ｒ＿ｄ）与吸附剂种类有关，与溶液中Ｉ￣－的平衡浓度（ｃ＿（ｅｑ））无关。Ｉ￣－在吸附剂上的浓度（ｃ＿ｓ）与其在溶液中的平衡浓度（ｃ＿（ｅｑ））的关系符合Ｆｒｅｕｎｄｌｉｃｈ方程。
The solubilities of AgI concentrated salt solutions are determined with radiochemicalmethod.The sorption behaviors of I￣- on cement,Fe(OH)_3 and rock salt in concentrated salt solu-tions are investigated with batch test.The experimental results show that in the above three sys-tems,when the concentration of I￣- is 10￣(-7)-10￣(-4)mol/l, the sorption ratios of I￣-(R_d)changewith the absorbent,but do not change with the equilibrium concentration of I￣-. For low I￣- con-centration sorption isotherms are linear and are in agreement with the empirical Freundlich equa-tion.
出处
《核化学与放射化学》
CAS
CSCD
北大核心
1995年第1期7-12,共6页
Journal of Nuclear and Radiochemistry
