摘要
本文用ＭＯ法研究氧分子的￣３∑￣－＿ｇ、￣１△＿ｇ和￣１∑￣＋＿ｇ三种自旋异构体的结构以及它们的反应活性，并对其进行理论分析。同时探讨了￣１△＿ｇ态氧化学在有机合成上的应用及氧分子通过光氧化反应和光敏氧化反应给人类带来潜在危害的机制。
Using Molecular Orbital Method we have studied the structure of three spinisomers(￣3∑￣-_g,￣1△_g,￣1∑￣+_g) about molecular oxygen and its reaction activity.Atthe sametime,inquire into the application at organic synthesis of ￣1△_g state oxygenchemistry and molecular oxygen by means of photooxidation or photosensitizedoxidating reaction bring about the mechanism of latent harm to humankind.
出处
《哈尔滨师范大学自然科学学报》
1995年第3期75-80,共6页
Natural Science Journal of Harbin Normal University
关键词
自旋异构体
氧分子
氧化学
反应活性
Spin isomers
Singlet state molecular oxygen
Oxygen molecule(ground State triplet form ￣3∑￣-_g)
Singlet state oxygen chemistry
Latent harm.
