摘要
新型层柱材料ＺｎＡｌ－ＸＷ_（１１）Ｃｏ的合成、表征及催化活性胡长文，刘彦勇，王作屏，张继余，王恩波（东北师范大学化学系，长春１３００２４）关键词层柱化合物，杂多阴离子，Ｋｅｇｇｉｎ结构，乙酸，正了醇，酯化化学组成通式为的阴离子粘土具有独特的层柱结构?..
Anionic clay pillared by triheteropolyoxometalates, ZnAl-XW11Co(X= Co, B or Ge),has been synthesized by ion exchange. The measurement results of XRD and IR confirm that the intercalation for XW11O39Co(H2O)n- takes place and results in gallery height of 0.99± 0.01um. The new pillared compounds are found to be efficient for esterification of acetic acid with n-butanol. It is found that the catalytic activityincreases as the negative charge of heteropolyoxometalates in ZnAlXW11Co decreases.
基金
国家自然科学基金
吉林大学无机水热合成开放研究实验室资助
关键词
杂多阴离子
酯化
层柱材料
催化活性
layer-pillared compound,heteropolyoxometalate, Kegginstructure, acetic acid, n-butanol, esterification
