摘要
用ＧＣ和ＧＣ／ＭＳ法研究了ＳＯ＿２，与１，３－丁二烯和１，３－戊二烯在无氧以及有氧体系中的光化学反应。确定了主要反应物，研究了体系的动力学，探讨了部分产物的生成机制。
The photochemical reactions of sulfur dioxide with l,3- butadienes and l,3-pentadienes inthe systems presence and absence of oxygen were studied.We observed the formation of smokefog andidentified a series of the products such as alcohols,aldehydes,ketones,esters,hydrocarbons and or-ganic sulfur compounds by means of GC/MS. According to the characteristic of such compounds and chemical kinetic theories,the mechanismof these photochemical reactions are suggested.These results are very important to the air pollutionchemistry.
出处
《吉林大学自然科学学报》
CAS
CSCD
1995年第3期100-102,共3页
Acta Scientiarum Naturalium Universitatis Jilinensis
基金
国家自然科学基金
