摘要
以N,N'-二芳基二硫代草酰胺与1,2-二溴乙烷进行S烷基化反应,合成了一系列2,3-双芳基亚氨基-1,4-二硫杂环己烷,反应在4h内完成,产率52%～62%.产物结构经元素分析,IR,1HNMR及MS表征,并以单晶X射线衍射分析进一步确证.
A series of 2,3-biarylimino-1,4-dithiacyclohexane compounds were synthesized by the sufur-alkylation of N,N'-diaryldithiooxamide with 1,2-dibromoethane in the presence of bases. The reactions were completed in 4 h and the yields were 52%similar to 62%. The structures of the products were established by elemental analysis, IR, H-1 NMR, MS spectra and X-ray diffraction analysis.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2005年第7期838-841,i004,共5页
Chinese Journal of Organic Chemistry
基金
江苏省教育厅自然科学基金(No.03KJB150009)
淮海工学院学科建设基金(No.XK200309)
淮海工学院自然科学基金(No.200312)资助项目
