摘要
邻菲罗啉及其衍生物被广泛用作配体,用于制备稀土金属螯合物而研制有机电致发光材料.合成了5-硝基-1,10-邻菲罗啉、5-氨基-1,10-邻菲罗啉、5-丙烯酰胺基-1,10-邻菲罗啉系列邻菲罗啉衍生物,利用熔点、红外、紫外、核磁共振氢谱、质谱等手段对合成的邻菲罗啉系列衍生物进行分析和表征,确证了它们的结构.
<Abstrcat>Phenanthroline and its derivatives were used as ligands of the lanthanide metal chelates which were used to prepare metallo-organic electroluminescent materials.(5-Nitro-1,10),phenanthroline,(5-amino-1,10)-phenanthroline and 5-acrylamido-1,10-phenanthroline were synthesizedand their synthesis routes were given. Phenanthroline derivatives were characterized and analyzed by infrared (IR), ultraviolet (UV),~1H nuclear magnetic resonance (~1HNMR), mass spectrometry (MS) and melting point method, thus, the structure of all these compounds have been comfirmed.
出处
《中南林学院学报》
CSCD
北大核心
2005年第3期103-105,共3页
Journal of Central South Forestry University
基金
中南林学院青年科学基金项目(编号0192).