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非线性光学晶体Na_3La_9O_3(BO_3)_8的生长研究 被引量:2

Study on the Growth of Nonlinear Optical Crystals Na_3La_9O_3(BO_3)_8
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摘要 以Na2CO3和H3BO3为助熔剂,Na2CO3和H3BO3摩尔比为7/6,熔质Na3La9O3(BO3)8和助熔剂摩尔比为1/10~1/14,采用顶部籽晶生长方法,生长Na3La9O3(BO3)8晶体,晶体尺寸为30×18×8mm3。本文讨论了籽晶方向对Na3La9O3(BO3)8晶体生长的影响,(100)方向比(001)方向更有利于晶体生长。 Na3La9O3(BO3)8 crystals with size up to 30 × 18 × 8 mm3 have been grown by the top-seeded solution growth (TSSG) method using Na2CO3 and H3BO3 as the flux. As flux systems, the suitable molar ratio of Na2CO3 and H3BO3 is 7/6. The suitable molar proportion of solute Na3La9O3(BO3)8 and flux is from 1/10 to 1/14. The effects of seed directions on the growth of Na3La9O3(BO3)8 crystals were discussed. And seeds along (100) direction are favorable for the growth of Na3La9O3(BO3)8 crystals.
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2005年第3期387-389,共3页 Journal of Synthetic Crystals
基金 国家自然科学基金(No.50372073)资助项目
关键词 硼酸镧钠 非线性光学晶体 顶部籽晶生长技术 Na_3La_9O_3(BO_3)_8 NLO crystals TSSG
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  • 1Chen C T, Wu Y C, Li R K. The Development of New NLO Crystals in the Borate Series [ J ]. Journal of Crystal Growth, 1990,99:790. 被引量:1
  • 2Gravereau P, Chaminade J P, Pechev S, et al. Na3La9O3(BO3)8, a New Oxyborate in the Ternary System Na2O-La2O3-B2O3: Preparation and Crystal Structure [ J ]. Solid State Sciences, 2002,4:993. 被引量:1
  • 3吴以成 张国春 傅佩珍 陈创天.化合物Na3La9B8O27非线性光学晶体及其制法和用途[P].CN Patent:01134393.1.2001-11-02. 被引量:3
  • 4Zhang G C, Wu Y C, Li Y G, et al. Flux Growth and Characterization of a New Oxyborate Crystal Na3La9O3(BO3)8 [ J ]. J of Crystal Growth,2005,275:1997-2001. 被引量:1

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