摘要
以1,4,5,8-四氮杂双环[4.4.0]癸烷为原料,经亚硝酸钠在盐酸中亚硝化、五氧化二氮在硝硫混酸介质中硝解,得到1,4,5,8-四硝基-1,4,5,8-四氮杂双环[4.4.0]癸烷,并用红外光谱和元素分析方法对产物进行了结构鉴定,产物收率达85%。
1,4,5,8-Tetranitro-1,4,5,8-tetraazabicyclo[4.4.0]decalin (TNAD) is used as an explosive and has several superior physical properties, such as heat-resistance and insensitivity to impact. This compound could be prepared from the raw material 1,4,5,8-tetraazabicyclo [4.4.0]decalin via nitrosation with sodium nitrite in hydrochloric acid, and followed nitrolysis with N_2O_5in mixed acid. In nitrolysis step, the effect of reaction medium and the reaction temperature on the yield have been investigated . The structure of compound was characterized by IR and elemental analysis.The total yield could reach as high as 85%.
出处
《火炸药学报》
EI
CAS
CSCD
2005年第2期50-51,共2页
Chinese Journal of Explosives & Propellants
