期刊文献+

无烟煤挥发分和焦炭独立燃烧过程中NO生成规律 被引量:15

Characteristics of NO release for the combustion of chars and volatiles of Anthracite
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摘要 采用固定床反应器,将无烟煤粉的燃烧分为焦炭燃烧和挥发分燃烧两部分,研究了各自燃烧过程中产生NO的规律,评价了焦炭N和挥发分N对煤粉燃烧产生NO的相对贡献。结果表明,煤粉N、焦炭N和挥发分N的转化率都随过量空气系数α和温度的增加而增加;焦炭N是无烟煤粉燃烧过程中NO的主要来源;煤粉的转化率都小于煤粉分解燃烧时挥发分转化率加焦炭的总转化率;还原性气氛或氧化性气氛越强,挥发分和焦炭在煤粉燃烧时的相互作用越强。 The experiments on the combustion of volatile and char of anthracite were carried out separately in a fixed-bed reactor. The NO release characteristics of volatile N and char N combustion and the relative contribution of volatile N and char N to NO formation of coal combustion were studied. It is found that coal N, volatile N and char N conversion increases as the excess air coefficient and temperature increase. Char N is the primary resources of NO formation during anthracite combustion. The coal N conversion is less than the total conversion of volatile N and char N, which is resulted from the interaction between volatile and char during coal combustion as it is in the reductive or oxidative atmosphere.
出处 《燃料化学学报》 EI CAS CSCD 北大核心 2005年第2期140-145,共6页 Journal of Fuel Chemistry and Technology
基金 国家重点基础研究发展规划项目(G1999022204-03)。~~
关键词 无烟煤 燃烧 NO析出 anthracite combustion NO release
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参考文献9

  • 1赵宗彬,李保庆.煤中矿物质对NO-半焦还原反应的影响[J].燃料化学学报,2001,29(2):129-134. 被引量:16
  • 2毛健雄等编著..煤的清洁燃烧[M].北京:科学出版社,1998:414.
  • 3岑可法 姚强 骆仲泱.高等燃烧学[M].杭州:浙江大学出版社,2000.584-587. 被引量:22
  • 4曹欣玉,牛志刚,应凌俏,王智化,周俊虎,刘建忠,岑可法.无烟煤燃料氮的热解析出规律[J].燃料化学学报,2003,31(6):538-542. 被引量:26
  • 5钟北京,张怀山,傅维标.煤焦燃烧NO释放规律研究[J].燃烧科学与技术,2000,6(1):28-31. 被引量:6
  • 6Mark Thomas K. The release of nitrogen oxides during char combustion[J]. Fuel,1997, 76(6): 457-473. 被引量:1
  • 7Yasuo Ohtsuka, Zhiheng Wu. Nitrogen release during fixed-bed gasification of several coals with CO2: factors controlling formation of N2[J]. Fuel, 1999, 78(1999): 521-527. 被引量:1
  • 8Shinji Kambara , Takayuki Takarada , Masaru Toyoshima. Relation between functional forms of coal nitrogen and NOx emissions from pulverized coal combustion[J]. Fuel, 1995, 74(9): 1247-1253. 被引量:1
  • 9Maria J Lazaro, Jose V lbarra, Rafael Moliner. The release of nitrogen during the combustion of coal chars : the role of volatile matter and surface area[J]. Fuel, 1996, 75(8): 1014-1024. 被引量:1

二级参考文献11

  • 1维列斯基TB,煤粉燃烧动力学,1986年 被引量:1
  • 2Guo F,Preprints American Chemical Society Division Fuel Chemistry,1996年,41卷,1期,160页 被引量:1
  • 3Chan L K,Combust Flame,1983年,52卷,1期,37页 被引量:1
  • 4毛健雄 毛健全 赵树民.煤的洁净燃烧[M].北京:科学出版社,1998.137-141. 被引量:9
  • 5Li Lian Tan, Chun-Zhu Li. Formation of NOx and SOx precursors during the pyrolysis of coal and biomass. Part Ⅰ. Effects of reactor configuration on the determined yields of HCN and NH3 during pyrolysis[J]. Fuel, 2000, 79(15):1883-1889. 被引量:1
  • 6Naoto Tsubouchi, Yasuo Ohtsuka. Nitrogen release during high temperature pyrolysis of coals and catalytic role of calcium in N2 formation[J]. Fuel, 2002, 81(18):2335-2342. 被引量:1
  • 7Yasuo Ohtsuka, Zhiheng Wu. Nitrogen release during fixed-bed gasification of several coals with CO2: factors controlling formation of N2[J]. Fuel, 1999, 78(5):521-527. 被引量:1
  • 8Chun-Zhu Li, Li Lian Tan. Formation of NOx and SOx precursors during the pyrolysis of coal and biomass.Part Ⅲ.Further discussion on the formation of HCN and NH3 during pyrolysis[J]. Fuel, 2000, 79(15):1899-1906. 被引量:1
  • 9Shinji K, Takayuki T, Masaru T, et al. Relation between functional forms of coal nitrogen and NOx emission from pulverized coal combustion[J]. Fuel, 1995, 74(9):1247-1253. 被引量:1
  • 10Johnsson J E. Formation and reduction of nitrogen oxides in fluidized-bed combustion[J]. Fuel, 1994, 73(9):1398-1415. 被引量:1

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