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定向凝固包晶合金带状组织的形成机制及相选择 Ⅰ.带状组织的形成机制 被引量:15

FORMATION MECHANISM OF BAND STRUCTURE AND PHASE SELECTION DURING DIRECTIONAL SOLIDIFICATION OF PERITECTIC ALLOYS Ⅰ.Formation Mechanism of Band Structure
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摘要 对定向凝固包晶合金在不同生长条件下,初生相和包晶相分别作为单相和充分形核相以低速平界面生长时,从初始到稳态的整个过渡区间,两相在界面及界面前沿液相中的溶质分布进行了分析.利用充分形核假设和成分过冷准则以及相稳定生长的最高界面温度判据,分析了初始过渡区内可能发生的第二相形核转变,确定了形成带状组织的成分条件.考虑到相生长的历史相关性,将带状组织区分为周期性带状组织区和单一带状组织区,更能够对实验现象进行合理的解释.对Ti-Al合金的计算结果与理论分析一致, Solute compositional distributions at and ahead of the solid-liquid interfaces are analyzed during the plane-front growth for both the primary and peritectic phases as single phase and nucleation phase for peritectic alloys directionally solidified at low growth rates from initial transient to steady state. Taking the nucleation and compositional undercooling criterion and assuming that the maximum interface growth temperature of phase growth is more stability during the directional solidification, the nucleation transitions during the transient period are investigated and compositional range of band structure formation is determined. Considering the history-dependant growths of a phase, the band structure can be differentiated as cycling band and single band structure, which can explain the experimental phenomena appropriately. The calculated results for Ti-Al alloy are identical with the theoretical analyses.
出处 《金属学报》 SCIE EI CAS CSCD 北大核心 2005年第6期593-598,共6页 Acta Metallurgica Sinica
基金 国家自然科学基金50395102黑龙江省杰出青年基金资助项目
关键词 包晶合金 定向凝固 带状组织 peritectic alloy,directional solidification,band structure
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