摘要
对甲基苯胺、氨基吡啶、乙二胺、氨基硫脲等与乙酰二茂铁环汞反应合成了一系列乙酰二茂铁亚胺和乙酰二茂铁亚胺环汞,其结构经1HNMR, IR和元素分析表征。其中[η5 - C5H4MeCNNHC(S)NH2 ]Fe(η5 - C5H5 )·1 /2CH2Cl2 经X 射线单晶衍射仪确证属三斜晶系,P- 1空间群,Mr=387. 12, a=7. 5939(2) , b=7. 8355(2) , c=14. 822(3) , α=92. 72(3)°, β=100. 62(3)°, γ=101. 92°, V=848. 2(3) 3, Z=2, ρC=2. 049mg·cm-3, μ=1. 323mm-1, F(000) =398,最终偏离因子R=0. 0537, wR=0. 1283。
A series of acylferrocenyl-imines and cyclomercurated acylferrocenyl-imines were synthesized by the reaction between amines(4-methyl benzenamine, 3-aminopyridine, ethylenediamine and thiosemicarbazide) and cyclomercurated acylferrocene. Their structures were characterized by 1H NMR, IR and elemental analysis. The crystal structure of [η 5-C_ 5H_ 4MeCNNHC(S)NH_ 2]Fe(η 5-C_ 5 H_ 5)· 1/2CH_ 2Cl_ 2 belongs to triclinic with space groups P-1 and the following crystallographic parameters: Mr=387.12, a= 7.5939 (2) , b=7.8355(2) , c=14.822(3) , α=92.72(3)°, β= 100.62(3)°, γ=101.92°, V=848.2(3) 3, Z=2, ρ_ C=2.049 mg·cm -3 , μ=1.323 mm -1 , F(000)=398, R=0.0537, wR=0.1283.
出处
《合成化学》
CAS
CSCD
2005年第3期244-248,i002,共6页
Chinese Journal of Synthetic Chemistry
关键词
乙酰二茂铁环汞
二茂铁亚胺
合成
晶体结构
cyclomercurated acylferrocene
ferrocenylimine
synthesis
crystal structure
