摘要
考察了固定床反应条件下负载磷钨酸合成直链烷基苯的工艺条件。结果表明:它有两种酸中心,在150～160℃预处理后活性高,对原料中的水敏感;低温活性高,2位产物异构体选择性好,并且在实验室中具有较好的活性稳定性。
The reaction conditions of supported heteropoly acid catalyst was examined in a fixed-bed reactor.The result shows that the catalyst has two kinds of acid center, with high activity when pretreated in 150～160 ?℃,and high sensitive to water, and can promote the alkylation reaction even in low temperature and produce more 2-phenylisomer. Furthermore, it has potential industrial utility due to its long catalytic stability.
出处
《北京化工大学学报（自然科学版）》
CAS
CSCD
北大核心
2005年第2期5-8,共4页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
基金
国家重点基础研究发展规划项目(G2000048046)
关键词
烷基化
磷钨酸
直链烷基苯
工艺条件
alkylation
phosphotungstic acid
linear alkylbenzene
reaction condition
