摘要
A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P212121. The crystal data are: a=0.530 78(17) nm, b=1.723 9(5) nm, c=2.456 9(8) nm, Z=4, μ=0.729 mm-1, Dc=1.579 g·cm-3, V=2.248 1(12) nm3, R1=0.033 1, ωR2=0.078 9. In the title complex, each Mn(Ⅱ) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo2- ligands. The γ-carboxyl coordinates to Mn(Ⅱ) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode. CCDC: 253910.
A one-dimensional double-chain coordination polymer [Mn(phen)(tsgluo)] was synthesized in a mixed solution and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic system with space group P2(1)2(1)2(1). The crystal data are: a=0.53078(17) nm, b = 1.7239(5) nm, c =2.4569(8) nm, Z=4, μ=0.729 mm(-1), D-c=1.579 gˆ cm(-3), V=2.2481(12) nm(3), R-1=0.0331, ω R-2=0.0789. In the title complex, each Mn(II) ion presents a octahedral geometry with the coordination of two nitrogen atoms from 1,10-phenanthroline and four oxygen atoms from three different tsgluo(2-) ligands. The γ-carboxyl coordinates to Mn(II) in the mode of bidentate chelate, while the α-carboxyl coordinates in a bidentate bridging mode.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2005年第5期689-692,共4页
Chinese Journal of Inorganic Chemistry
基金
广西自然科学基金资助项目(No.0229004)。
