摘要
酞菁氧钛以联环己烷为溶剂，以邻苯二脂及四氯化钛直接反应生成。其优点是便于分离及纯化。同时对各晶型的获得及晶型间的相互转化进行了研究，并以Ｘ－射线粉末衍射及ＦＴ－ＩＲ进行了表征，并记录了不同晶型的酞菁氧钛在室温硫化硅橡胶中的吸收光谱。
Oxotitanium phthalocyanine was synthesized from phthalonitrile and titanium te-trachloride in bicyclohexyl.It is much more convenient to separate and purify the productsby using bicyclohexyl as a solvent. Five polymorphs were obtained and characterized by X-ray powder diffractometry and FTIR spectroscopy. The absorption spectra of the poly-morphs in silicone rubbers were recorded.
出处
《应用化学》
CAS
CSCD
北大核心
1994年第1期72-75,共4页
Chinese Journal of Applied Chemistry
关键词
酞菁氧钛
合成
晶型
有机光导材料
oxotitanium phthalocyanine,synthesis, crystal form,organic photoconductor
