摘要
合成了标题卟啉配体及其钴、镍、铜、锌和铁的五种配合物．对它们进行了元素分析、ＵＶ、ＩＲ和荧光光谱等结构表征．用ＤＴＡ、ＴＧ、ＤＳＣ等手段研究了这些新化合物的热稳定性及热分解机理，实验结果与ＨＭＯ方法计算的结果一致．
Five new complexes of the title porphyrin have been synthesized, their structures were characterized by elemental analysis, UV, IR, fluorcsccncc spectrum and so on, Their thermal stability and thermal decomposition mechanism were studied by DTA,TG, DSC and GC method. The experiment result are in accord with the calculational result from HMO method.
出处
《无机化学学报》
CSCD
北大核心
1994年第2期141-145,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金
关键词
卟啉配合物
热分解机理
结构表征
metalporphyrin complex thermal decomposition mechanism
