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用二氧化氯降解废水中的苯胺类化合物(2)──降解机理的探讨 被引量:5

A STUDY ON THE DEGRADATION OF BENZYLAMINE COMPOUNDS IN WATER BY THE OXIDATION OF CHLORINGE DIOXIDE Ⅱ.A STUDY OF MECHANISM OF MECHANISM OF DEGRADATION
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摘要 本文在上文(1)的基础上,进一步研究了经二氧化氯处理前后BOD_5/COD的变化规律,其比值大于或接近0.3.其降解产物有醌及醌的氧化产物和NHI.对苯胺及二氧化氯来说其.反应级数为1,整个反应为二级反应. BOD_5 and the ratio of BOD5/COD(0. 3-0. 3) obviously improved ofter treatment by CIO2. This improved the possiblity of bio-degradation. After studying on the reaction between CIO2 and aniline,quinone and ammonium ions were found to be formed as intemediates. It was the first order reaction for ClO2 or aniline.The reaction could be written as: other intermediates→final products It could be concluded that CLO2 was suitable to degrade aromatic amine compound in wastewater.
机构地区 四川大学
出处 《环境保护科学》 CAS 1994年第4期29-31,36,共4页 Environmental Protection Science
关键词 二氧化氯 苯胺类化合物CODBOD_5降解机理 Choloring Dioxide Aromatic Amine Compounds,COD BOD5 Mechanism of Degra dation.
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