摘要
苯胺气相N-烷基化反应研究Ⅱ.苯胺和乙醇常压催化合成N-乙基苯胺的工业应用陈骏如,李瑞祥,韩银仙,李贤均(四川大学化学系成都610064)N-乙基苯胺是制造染料、塑料、炸药和医药等许多化工产品的重要中间体,其合成方法过去多采用无机酸催化剂,如H_2S...
Industrial Production of N-cthylaniline and N,N-diethylaniline using solid acid as catalyst has been developed. When the reaction is carried out under the conditions:vapor phase,atmospheric pressure,T=295-305℃’C_6H_5NH_2/C_2H_5OH=1:2 mole ratio),LHSV=0. 6h ̄(-1) ,the conversion of aniline is about 80-85%and the selectivity for N-ethytaniline is about 82-86%,The another product is N. N-diethylaniline.
出处
《化学研究与应用》
CSCD
1994年第1期87-91,共5页
Chemical Research and Application
关键词
苯胺
烷基化反应
乙基萃胺
乙醇
N-Ethylation of A niline
N-Ethylaniline
N
N-Diethylaniline.Vapor-phase method