摘要
本文对交互校验可变内标法进行了介绍，并应用于ＸＲＦ测定Ｚｎ、Ｃｄ、Ｎｉ、Ｃｕ中选择内标元素，提出了以ＰＡＮ膜富集ＸＲＦ薄膜法测定工业废水及人发中微量Ｚｎ、Ｃｄ、Ｎｉ、Ｃｕ的新方法。方法检出限（μｇ／ｃｍ２）分别为Ｚｎ０．０７８，Ｃｄ０．１５，Ｎｉ０．０５９，Ｃｕ０．０７６。测定方法简便准确。
The cross-check variable internal standard method is described and is applicated to selection of variable internal standard element in the determination of Zn,Cd, Ni,Cu by X-ray fluoresence spectrometry. A new method is described for the determination of trace amounts of Zn,Cd,Ni,Cu in waste and human hair by XRF after preconcentration with PAN polyacrylonitrile membrane. The detection limits of Zn,Cd. Ni,Cu are 0.078.0.15,0.059,0.076 μg/cm2, respectively. The method proposed is simple and accurate.
出处
《光谱实验室》
CAS
CSCD
1994年第6期43-48,共6页
Chinese Journal of Spectroscopy Laboratory
关键词
XRF
PAR膜
交互检验内标法
锌
镉
镍
钼
富集
Zinc,Cadmium,Nickel,Copper.X-ray Fluorescence Spectrometry,Waste, Human Hair, PAN Polyacrylonitrile Membrane,Cross-Check Variable Internal Standarl Method.
