摘要
以ＡＰＳ为引发剂，研究了丙烯酰胺与烯丙基磺酸钠的水溶液共聚合反应，考察了单体配比、反应温度、ＡＰＳ浓度等对共聚反应的影响。用ＩＲ、１Ｈ－ＮＭＲ和［η］对共聚物进行了表征，并用１Ｈ－ＮＭＲ谱测定了共聚物的组成，计算出了３０℃时共聚单体的竞聚率。
The copolymerization of acrylamide with sodium allylsulfonate in aqueous solution using ammonium persulfate as the initiator was studied.The copolymers were characterized by IR and￣1HNMR spectroscopies. And the reactivity ratios(r1=2. 67,r2=0. 31, 30.0℃) were calculated by Kelen-Tudos method and Finoman-Ross method. The flocculation of Kaolin suspension contained salt with the copolymers was also studied.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1994年第2期73-77,共5页
Polymer Materials Science & Engineering
关键词
丙烯酰胺
烯丙基磺酸钠
共聚
s: copolymerization
acrylamide
sodium allylsulfonate
flocculation.
