摘要
交替马来酸酐共聚物多缩乙二醇酯盐络合物的离子传导性丁黎明，林云青，周子南，王佛松（中国科学院长春应用化学研究所，长春，１３００２２）关键词高分子固体电解质，离子电导率，玻璃化转变温度，离子传输，ＶＴＦ方程１９７３年，Ｐ．Ｖ．Ｗｒｉｇｈｔ等人［１］首次...
In this paper, the ionic conductivity of the BM350-LiClO4 complexes was studied as a function of temperature and salt concentration.At high salt concentrations,the more pronounced fall in conductivity in the solid medium has been interpreted as being due to the effect of Tg and bulk viscosity on ion transport. Conductivities which displayed non-Arrhe-nius behviour were analysed using the Vogel-Tammann-Fulcher equation and interpreted on the basis of the configurational entropy model derived by Gibbs and coworkers.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1994年第11期1727-1729,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
马来酸酐
乙二醇酯盐
络合物
离子传导
Solid polymer electrolytes,Ionic conductivity, Glass transition temperature,Ion transport,VTF equation
