摘要
用分光光度法研究了铜 ( )与四苯基卟啉在溶剂 DMF中生成 Cu TPP的动力学以及镉 ( )离子对该反应的催化作用 ,提出反应机理 ,并研究了温度及溶剂效应对反应动力学参数的影响 ,求得基元反应的活化参数 △ H≠m、△S≠m 及前置平衡步的△HΘm、△SΘm。
Kinetics of formation of tetraphenylporphrinatocopper(Ⅱ) in DMF had been studied spectrophotometry in the presence of cadmium(Ⅱ) ion.The effect of solvent on the reactions were discussed.The mechanisms of reaction were proposed.The activation parameters △H≠ m、△S≠ m [WT5”BZ]of elementary step,the standard molar enthalpy change △HΘ m and the standard molar entropy △SΘ m change of pre-equilibrium step had been calculated.
出处
《湖北师范学院学报（自然科学版）》
2000年第3期40-43,共4页
Journal of Hubei Normal University(Natural Science)
关键词
四苯基卟啉铜(Ⅱ)反应动力学
反应机理
催化作用
溶剂效应
tetraphenylporphrinatocoopper(Ⅱ)
mechanism of reaction
kinetics of formation reaction
catalysis of Cd 2+ ion
effect of solvent
