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Non-covalent associative structure of coal 被引量:2

Non-covalent associative structure of coal
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摘要 The recent progress of non-covalent associative structure of coal, and the mechanisms of the CS2/NMP (1:1 by volume) mixed solvent and the additive addition enhancing the extraction yield of coals were reviewed, and the aggregation behavior of coal in solid and solution states were presented, and the aggregation behavior of coal in solid and solution states were introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS2/NMP (1:1 by volume) is a unique solvent to give high extraction yields for some bituminous coals. Some additives can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent. The recent progress of non-covalent associative structure of coal, and the mechanisms of the CS2/NMP (1:1 by volume) mixed solvent and the additive addition enhancing the extraction yield of coals were reviewed, and the aggregation behavior of coal in solid and solution states were presented, and the aggregation behavior of coal in solid and solution states were introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS2/NMP (1:1 by volume) is a unique solvent to give high extraction yields for some bituminous coals. Some additives can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent.
作者 水恒福
出处 《Journal of Coal Science & Engineering(China)》 2004年第1期60-64,共5页 煤炭学报(英文版)
基金 Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of MOE and the Natural Scientific Foundation of Anhui Education Department (2003kj052)
关键词 COAL ASSOCIATIVE STRUCTURE solvent extraction SWELLING 溶剂萃取 非共价联合结构 膨胀 NMR IR XRD
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