The Effect of 19-Substituent on the Stereospecific Hydroxylation of △~5-Steroids Using Performic Acid as Oxidant

The Effect of 19-Substituent on the Stereospecific Hydroxylation of △~5-Steroids Using Performic Acid as Oxidant

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摘要 In the studying of the stereospecific hydroxylation of different Δ5-steroids with performic acid, followed by hydrolysis with CH3OH/KOH, we found 19-substituting groups considerably affected the reaction and we put forward the mechanism. In the studying of the stereospecific hydroxylation of different Δ5-steroids with performic acid, followed by hydrolysis with CH3OH/KOH, we found 19-substituting groups considerably affected the reaction and we put forward the mechanism.

作者 WeiGangLU JingYuSU LongMeiZENG HongLI

机构地区 SchoolofChemistryandChemicalEngineering

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第8期899-902,共4页 中国化学快报（英文版）

关键词 △~5-Steroids performic acid 19-substituting group hydroxylation. △~5-Steroids, performic acid, 19-substituting group, hydroxylation.

分类号 O629.2 [理学—有机化学]

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1G. Y. S. Wang,F. Y. Li,L. M. Zeng,Chem. J. Chin. Univ . 1992 被引量：1
2C. Y. Duh,S. K. Wang,M. J. Chu,J. Nad. Production Journal . 1998 被引量：1
3W. G. Lu,M. Y. Wang,J. Y. Su,L. M. Zeng,Chin. Chemistry Letters . 2002 被引量：1

1LI Lan,LIN Xiao-yan,LI Zong-he.Hydroxylation Reaction Mechanism for Nitrosodimethylamine by Oxygen Atom[J].Chemical Research in Chinese Universities,2011,27(6):1006-1009. 被引量：1
2张富民,郭麦平,葛汉青,王军.Hydroxylation of Benzene with Hydrogen Peroxide over Highly Efficient Molybdovanadophosphoric Heteropoly Acid Catalysts[J].Chinese Journal of Chemical Engineering,2007,15(6):895-898. 被引量：8
3Zhang Pingyu,Wang Wei,Wu Jigui.Preparation of Heteropoly Molybdoselenite Complex and Its Lanthanide Salts and Their Catalysis for Hydroxylation of Phenol[J].Journal of Rare Earths,2006,24(2).
4Ling Jie GAO and Tian Zeng ZHAO,Guang Dian HAN(The Institute of Chemistry, Henan Academy of Sciences, Zhengzhou, 450002)(Institute of Materia Medica, Peking Union Medical College,Chinese Academy of Medical Sciences, Beijing 100050).A Convenient Method for the Stereoselective Synthesis of 7αHydroxycholesterol[J].Chinese Chemical Letters,1998,9(8):715-716.
5Rong Xiao Xiao Yu Su Ru Gang Xie.The complexes of multiimidazole with copper(Ⅰ) display tyrosinase activity[J].Chinese Chemical Letters,2007,18(10):1278-1280.
6Yuan Jiang PAN,Yao Zu CHEN(Department of Chemistry, Zhejiang University, Hangzhou 310027).A Novel Approach for Determining the Orientation of 3-Hydroxyl Group of Some Steroids by CIMS[J].Chinese Chemical Letters,1999,10(2):143-144.
7张芳江,熊文南,姜标.A Convenient Stereospecific Synthesis of Trifluoromethyl Substituted Polyfunctionalized Cyclopropane[J].厦门大学学报（自然科学版）,1999,38(S1):170-170.
8李文华,王锦华,胡振元.STUDIES ON FLUORO-ALKYL BONDED PHASE AS HPLC PACKING[J].Chinese Science Bulletin,1982,27(5):574-575.
9Yang, BH,Jiang, JQ,Huang, XL,Wu, HM.A new strategy for the stereospecific syntheses of C-furanosides[J].Chinese Journal of Chemistry,1997,15(2):178-187.
10许杏祥,朱杰,周维善.THE STEREOSPECIFIC SYNTHESIS OF ARTEANNUIN B[J].Chinese Science Bulletin,1983,28(6). 被引量：1

Chinese Chemical Letters

2004年第8期

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The Effect of 19-Substituent on the Stereospecific Hydroxylation of △~5-Steroids Using Performic Acid as Oxidant

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