摘要
三氟甲基磺酸铜 [Cu(OTf) 2 ]与各种手性磷氮配体络合催化不对称合成已取得了巨大进展 .
Copper(II) triflate chiral derivatives chelated with bis(oxazoline)s, phosphoramidites, phosphites, phosphonites or other C 2-symmetric chiral ligands have been extensively studied as excellent chiral catalysts in asymmetric synthesis. This review describes in detail the recent advances in the application of these chiral copper(II) catalysts in enantioselective cycloaddition, aldol, conjugate addition, carbonyl-ene and cyclopropanation reactions.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2004年第10期1159-1167,共9页
Chinese Journal of Organic Chemistry
基金
曲靖师范学院科研基金 (No.0 31 390 4 )资助项目
