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超声波作用下锌粉诱发芳香醛的还原偶联反应(英文) 被引量:2

Reductive Coupling of Aromatic Aldehydes Using Zinc Powder in Aqueous Sodium Hydroxide under Ultrasound
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摘要 超声波作用下 ,芳香醛在Zn -1 0 %NaOH(aq.) -MeOH体系中反应 ,室温下 2 5min~ 60min内得到 41 %~ 97%的偶联产物邻二醇。 The reductive coupling of aromatic aldehydes was carried out under ultrasound irradiation in a Zn-10%NaOH(aq.)-MeOH system at rt for 25min~60min, which gave vicinal diol in 41%~97% yield.
出处 《合成化学》 CAS CSCD 2004年第5期429-431,434,共4页 Chinese Journal of Synthetic Chemistry
基金 theNaturalScienceFoundationofHebeiProvince( 2 0 3 1 0 7) SupportedbytheScienceFoundationofLangfangNormalCollege( 2 0 0 3 0 8)
关键词 超声波 金属锌 邻二醇 还原偶联 ultrasound irradiation metal Zinc vicinal diol reductive coupling
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参考文献4

  • 1Wang L,Sun X H,Zhang Y M. Reductive Coupling of Carbonyl Compounds to Pinacols Using Zinc Powder in Aqueous Media[J].J Chem Research,1998:336-337. 被引量:1
  • 2Tanaka K,Kithigami S,Toda F. A New Method for Coupling Aromatic Aldehydes and Ketones to Produce Glycols Using Zn-ZnCl2 in Aqueous Solution and in the Solid State[J].J Org Chem,1990,55:2981-2983. 被引量:1
  • 3Zhang W C,Li C J. Magnesium in Water:Simple and Effective for Pinacol-Coupling[J].J Chem Soc Perkin Trans,1998,64:3131-3132. 被引量:1
  • 4Bian Y J,Liu S M,Li J T,Li T S. Pinacol Coupling of Aromatic Aldehydes Using Aluminium under Ultrasound Irradiation[J].Synth Commun,2000,32(8):1169-1173. 被引量:1

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