摘要
以脱氢枞胺为原料,经氨基酰化、12位乙酰化、与对甲苯磺酰肼形成对甲苯磺酰腙衍生物,再通过卡宾中间体与C60进行[2+1]环加成反应合成了C60-脱氢枞胺衍生物。目标化合物经IR,UV-Vis,1H NMR,13C NMR,MALDI-TOF MS表征,所得化合物为[6,6]闭环结构C60加成产物。
The C60-dehydroabietylamine derivative was synthesized from dehydroabietylamine via amidation,12-acetylation and reaction with p-tosylhydrazide to give the corresponding p-tosylhydrazone,followed by [2 + 1]-cycloaddition of the carbene intermediate with C60. The structure was characterized by IR,UV-Vis,1H NMR,13 C NMR,MALDI-TOF MS. The results showed that the titled compound is [6,6]-closed C60 adduct.
出处
《化学通报》
CAS
CSCD
北大核心
2015年第1期80-84,共5页
Chemistry
基金
国家自然科学基金项目(31170536)资助
关键词
脱氢枞胺
富勒烯
环加成
合成方法
Dehydroabietylamine,Fullerenes,Cycloaddition,Synthesis methods
